C2fd20153d 365..378

نویسندگان

  • Qian He
  • Peter J. Miedziak
  • Lokesh Kesavan
  • Nikolaos Dimitratos
  • Meenakshisundaram Sankar
  • Jose Antonio Lopez-Sanchez
  • Michael M. Forde
  • Jennifer K. Edwards
  • David W. Knight
  • Stuart H. Taylor
  • Christopher J. Kiely
  • Graham J. Hutchings
چکیده

Trimetallic Au–Pd–Pt nanoparticles have been supported on activated carbon by the sol-immobilisation method. They are found to be highly active and selective catalysts for the solvent-free aerobic oxidation of benzyl alcohol. The addition of Pt promotes the selectivity to the desired product benzaldehyde at the expense of toluene formation. Detailed aberration corrected STEM-XEDS analysis confirmed that the supported particles are indeed Au–Pd–Pt ternary alloys, but also identified composition fluctuations from particle-to-particle which vary systematically with nanoparticle size.

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تاریخ انتشار 2013